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4'-Iodoacetophenone

  • Name 4'-Iodoacetophenone
  • CAS 13329-40-3
  • Purity 99%
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Product Details

Factory Sells Best Quality 4'-Iodoacetophenone 13329-40-3 with GMP standards

  • Molecular Formula: C8H7IO
  • Molecular Weight: 246.047
  • Appearance/Colour: brown crystalline powder 
  • Vapor Pressure: 0.0039mmHg at 25°C 
  • Melting Point: 82-84 °C(lit.) 
  • Refractive Index: 1.603 
  • Boiling Point: 279.9 °C at 760 mmHg 
  • Flash Point: 123.1 °C 
  • PSA: 17.07000 
  • Density: 1.72 g/cm3 
  • LogP: 2.49380 

4'-Iodoacetophenone(Cas 13329-40-3) Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 94, p. 5106, 1972 DOI: 10.1021/ja00769a066The Journal of Organic Chemistry, 48, p. 4394, 1983 DOI: 10.1021/jo00171a050

General Description

Pd(0)-catalyzed cross coupling reaction of 4′-iodoacetophenone with siloxane has been reported. Heck-Mizoroki reactions of 4′-iodoacetophenone with styrene catalyzed by Pd nanoparticles in the flow reactor has been reported.

InChI:InChI=1/C8H7IO/c1-6(10)7-2-4-8(9)5-3-7/h2-5H,1H3

13329-40-3 Relevant articles

A facile and sustainable protocol to the preparation of aryl iodides using stable arenediazonium bis(trifluoromethylsulfonyl)imide salts via the telescopic process

Khaligh, Nader Ghaffari

, (2018)

The preparation of aryl iodides in a tel...

Palladium-catalyzed, sequential, three-component cross-coupling of aryl halides, alkynes, and arynes

Liu, Zhijian,Larock, Richard C.

, p. 2535 - 2538 (2007)

(Chemical Equation Presented) Three's a ...

Nitrite ionic liquid as a new reagent for in situ synthesis of aryl iodides and azides

Eshghi, Hossein,Bakavoli, Mehdi,Ghasemzadeh, Marjan

, p. 3999 - 4007 (2013)

A new ionic liquid, 1-methyl-3-(2-[2-(1-...

Aryl diazonium nanomagnetic sulfate and potassium iodide: An iodination process

Kolvari, Eskandar,Amoozadeh, Ali,Koukabi, Nadiya,Otokesh, Somayeh,Isari, Mohsen

, p. 3648 - 3651 (2014)

A simple and efficient procedure for the...

PREPARATION OF AROMATIC IODIDES FROM BROMIDES VIA THE REVERSE HALOGEN EXCHANGE

Suzuki, Hitomi,Kondo, Akiko,Ogawa, Takuji

, p. 411 - 412 (1985)

Aromatic bromides undergo halogen exchan...

Metal-free iodination of arylboronic acids and the synthesis of biaryl derivatives

Niu, Liting,Zhang, Hao,Yang, Haijun,Fu, Hua

, p. 995 - 1000 (2014)

A simple, general and efficient method i...

The dehydrogenative oxidation of aryl methanols using an oxygen bridged [Cu-O-Se] bimetallic catalyst

Choudhury, Prabhupada,Behera, Pradyota Kumar,Bisoyi, Tanmayee,Sahu, Santosh Kumar,Sahu, Rashmi Ranjan,Prusty, Smruti Ranjita,Stitgen, Abigail,Scanlon, Joseph,Kar, Manoranjan,Rout, Laxmidhar

supporting information, p. 5775 - 5779 (2021/04/12)

Herein, we report a new protocol for the...

The Reactivity of α-Fluoroketones with PLP Dependent Enzymes: Transaminases as Hydrodefluorinases

García-Ramos, Marina,Cuetos, Aníbal,Kroutil, Wolfgang,Grogan, Gideon,Lavandera, Iván

, p. 3967 - 3972 (2021/08/09)

A chemical method for the treatment of h...

Palladium-Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand-Assisted Halide Exchange

Boehm, Philip,Cacherat, Bastien,Lee, Yong Ho,Martini, Tristano,Morandi, Bill

supporting information, p. 17211 - 17217 (2021/07/02)

We report an efficient and broadly appli...

Selective electrochemical oxidation of aromatic hydrocarbons and preparation of mono/multi-carbonyl compounds

Li, Zhibin,Zhang, Yan,Li, Kuiliang,Zhou, Zhenghong,Zha, Zhenggen,Wang, Zhiyong

, p. 2134 - 2141 (2021/09/29)

A selective electrochemical oxidation wa...

13329-40-3 Process route

para-bromoacetophenone
99-90-1

para-bromoacetophenone

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

4,4'-diacetylbiphenyl
787-69-9

4,4'-diacetylbiphenyl

Conditions
Conditions Yield
With tributylphosphine; potassium iodide; nickel dibromide; In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide; at 50 ℃; for 1.5h;
76 % Chromat.
22 % Chromat.
1-(p-acetophenyl)-3,3-diethyl-1-triazene
86452-55-3

1-(p-acetophenyl)-3,3-diethyl-1-triazene

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
Conditions Yield
With chloro-trimethyl-silane; sodium iodide; In acetonitrile; at 60 ℃; for 0.0833333h;
92%

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