4'-Iodoacetophenone
- Name 4'-Iodoacetophenone
- CAS 13329-40-3
- Purity 99%
Product Details
Factory Sells Best Quality 4'-Iodoacetophenone 13329-40-3 with GMP standards
- Molecular Formula: C8H7IO
- Molecular Weight: 246.047
- Appearance/Colour: brown crystalline powder
- Vapor Pressure: 0.0039mmHg at 25°C
- Melting Point: 82-84 °C(lit.)
- Refractive Index: 1.603
- Boiling Point: 279.9 °C at 760 mmHg
- Flash Point: 123.1 °C
- PSA: 17.07000
- Density: 1.72 g/cm3
- LogP: 2.49380
4'-Iodoacetophenone(Cas 13329-40-3) Usage
|
Synthesis Reference(s) |
Journal of the American Chemical Society, 94, p. 5106, 1972 DOI: 10.1021/ja00769a066The Journal of Organic Chemistry, 48, p. 4394, 1983 DOI: 10.1021/jo00171a050 |
|
General Description |
Pd(0)-catalyzed cross coupling reaction of 4′-iodoacetophenone with siloxane has been reported. Heck-Mizoroki reactions of 4′-iodoacetophenone with styrene catalyzed by Pd nanoparticles in the flow reactor has been reported. |
InChI:InChI=1/C8H7IO/c1-6(10)7-2-4-8(9)5-3-7/h2-5H,1H3
13329-40-3 Relevant articles
A facile and sustainable protocol to the preparation of aryl iodides using stable arenediazonium bis(trifluoromethylsulfonyl)imide salts via the telescopic process
Khaligh, Nader Ghaffari
, (2018)
The preparation of aryl iodides in a tel...
Palladium-catalyzed, sequential, three-component cross-coupling of aryl halides, alkynes, and arynes
Liu, Zhijian,Larock, Richard C.
, p. 2535 - 2538 (2007)
(Chemical Equation Presented) Three's a ...
Nitrite ionic liquid as a new reagent for in situ synthesis of aryl iodides and azides
Eshghi, Hossein,Bakavoli, Mehdi,Ghasemzadeh, Marjan
, p. 3999 - 4007 (2013)
A new ionic liquid, 1-methyl-3-(2-[2-(1-...
Aryl diazonium nanomagnetic sulfate and potassium iodide: An iodination process
Kolvari, Eskandar,Amoozadeh, Ali,Koukabi, Nadiya,Otokesh, Somayeh,Isari, Mohsen
, p. 3648 - 3651 (2014)
A simple and efficient procedure for the...
PREPARATION OF AROMATIC IODIDES FROM BROMIDES VIA THE REVERSE HALOGEN EXCHANGE
Suzuki, Hitomi,Kondo, Akiko,Ogawa, Takuji
, p. 411 - 412 (1985)
Aromatic bromides undergo halogen exchan...
Metal-free iodination of arylboronic acids and the synthesis of biaryl derivatives
Niu, Liting,Zhang, Hao,Yang, Haijun,Fu, Hua
, p. 995 - 1000 (2014)
A simple, general and efficient method i...
The dehydrogenative oxidation of aryl methanols using an oxygen bridged [Cu-O-Se] bimetallic catalyst
Choudhury, Prabhupada,Behera, Pradyota Kumar,Bisoyi, Tanmayee,Sahu, Santosh Kumar,Sahu, Rashmi Ranjan,Prusty, Smruti Ranjita,Stitgen, Abigail,Scanlon, Joseph,Kar, Manoranjan,Rout, Laxmidhar
supporting information, p. 5775 - 5779 (2021/04/12)
Herein, we report a new protocol for the...
The Reactivity of α-Fluoroketones with PLP Dependent Enzymes: Transaminases as Hydrodefluorinases
García-Ramos, Marina,Cuetos, Aníbal,Kroutil, Wolfgang,Grogan, Gideon,Lavandera, Iván
, p. 3967 - 3972 (2021/08/09)
A chemical method for the treatment of h...
Palladium-Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand-Assisted Halide Exchange
Boehm, Philip,Cacherat, Bastien,Lee, Yong Ho,Martini, Tristano,Morandi, Bill
supporting information, p. 17211 - 17217 (2021/07/02)
We report an efficient and broadly appli...
Selective electrochemical oxidation of aromatic hydrocarbons and preparation of mono/multi-carbonyl compounds
Li, Zhibin,Zhang, Yan,Li, Kuiliang,Zhou, Zhenghong,Zha, Zhenggen,Wang, Zhiyong
, p. 2134 - 2141 (2021/09/29)
A selective electrochemical oxidation wa...
13329-40-3 Process route
-
-
99-90-1
para-bromoacetophenone
-
-
13329-40-3
4-Iodoacetophenone
-
-
787-69-9
4,4'-diacetylbiphenyl
| Conditions | Yield |
|---|---|
|
With
tributylphosphine; potassium iodide; nickel dibromide;
In
N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
at 50 ℃;
for 1.5h;
|
76 % Chromat.
22 % Chromat. |
-
-
86452-55-3
1-(p-acetophenyl)-3,3-diethyl-1-triazene
-
-
13329-40-3
4-Iodoacetophenone
| Conditions | Yield |
|---|---|
|
With
chloro-trimethyl-silane; sodium iodide;
In
acetonitrile;
at 60 ℃;
for 0.0833333h;
|
92%
|
13329-40-3 Upstream products
-
99-92-3
p-aminobenzophenone
-
591-50-4
iodobenzene
-
75-36-5
acetyl chloride
-
917-54-4
methyllithium
13329-40-3 Downstream products
-
607-43-2
6-iodo-2-(4-iodo-phenyl)-quinoline-4-carboxylic acid
-
68120-56-9
1-(4-iodophenyl)ethanol
-
95023-29-3
{2-[1-(4-iodo-phenyl)-1-phenyl-ethoxy]-ethyl}-dimethyl-amine
-
94089-31-3
1-iodo-4-(1-phenylvinyl)benzene
Related products
-
2-(bicyclo[2.2.1]hept-5-en-2-ylmethylene)heptan-1-al
CAS:85392-35-4
-
1,3-Cyclopentanedione
CAS:3859-41-4
-
5-chloro-alpha-(hydroxyimino)thiophen-2-acetonitrile
CAS:42520-76-3
-
SILVER POTASSIUM IODIDE
CAS:12041-40-6